#Shrinky Dinks close the gap for nanowires How do you put a puzzle together when the pieces are too tiny to pick up?
to close the gap between nanowires in an array to make them useful for high-performance electronics applications.
Nanowires are extremely fast, efficient semiconductors, but to be useful for electronics applications, they need to be packed together in dense arrays.
Researchers have struggled to find a way to put large numbers of nanowires together so that they are aligned in the same direction and only one layer thick."
"Chemists have done already a brilliant job in making nanowires exhibit very high performance. We just don't have a way to put them into a material that we can handle,
people can make nanowires and nanotubes using any method they like and use the shrinking action to compact them into a higher density."
"The researchers place the nanowires on the Shrinky Dinks plastic as they would for any other substrate,
but then shrink it to bring the wires much closer together. This allows them to create very dense arrays of nanowires in a simple, flexible and very controllable way.
The shrinking method has added the bonus of bringing the nanowires into alignment as they increase in density.
Nam's group demonstrated how even wires more than 30 degrees off-kilter can be brought into perfect alignment with their neighbors after shrinking."
and the low cost of plastic could have a huge impact on nanowire assembly and processing for applications."
For example, experiments have shown that film made of packed nanowires has properties that differ quite a bit from a crystal thin film."
made of densely packed nanowires, that could harvest energy from light much more efficiently than traditional thin-film solar cells s
of Nanotechology) and their colleagues have succeeded now in producing a novel type of nanofiber whose highly ordered and porous structure gives it an extraordinarily high surface-to-volume ratio.
#Chirality-controlled growth of single-walled carbon nanotubes Recently, Professor Li Yan's research team developed a novel strategy to produce single-walled carbon nanotubes with specific chirality by applying a new family of catalysts,
Single-walled carbon nanotube (SWNT which can be considered as a seamlesscylinder formed by rolling a piece of graphene,
"the main hurdle (of carbon-based electronics) is our current inability to produce large amounts of identical nanostructureshere is no reliable way to directly produce a single CNT type such as will be needed in a large integrated system."
Experimental evidence and theoretical simulation reveal that the good structural match between the carbon atom arrangement around the nanotube circumference
"The chirality-specific growth of single-walled carbon nanotubes is the most challenging and important issue in the field,
#Lab unzips nanotubes into ribbons by shooting them at a target (Phys. org) Carbon nanotubes unzipped into graphene nanoribbons by a chemical process invented at Rice university are finding use in all kinds of projects
The Rice lab of materials scientist Pulickel Ajayan discovered that nanotubes that hit a target end first turn into mostly ragged clumps of atoms.
But nanotubes that happen to broadside the target unzip into handy ribbons that can be used in composite materials for strength
The researchers fired pellets of randomly oriented multiwalled carbon nanotubes from a light gas gun built by the Rice lab of materials scientist Enrique Barrera with funding from NASA.
When they inspected the resulting carbon rubble they found nanotubes that smashed into the target end first
or at a sharp angle simply deformed into a crumpled nanotube. But tubes that hit lengthwise actually split into ribbons with ragged edges.
Single-wall nanotubes do just the opposite; when the tube flattens the bottom wall hits the inside of the top wall
Ozden explained that the even distribution of stress along the belly-flopping nanotube which is many times longer than it is wide breaks carbon bonds in a line nearly simultaneously.
The researchers said 70 to 80 percent of the nanotubes in a pellet unzip to one degree or another.
Ozden said the process eliminates the need to clean chemical residues from nanoribbons produced through current techniques.
#Diamond plates create nanostructures through pressure not chemistry You wouldn't think that mechanical forcehe simple kind used to eject unruly patrons from bars,
and original method uses simple pressure kind of high-tech embossingo produce finer and cleaner results in forming silver nanostructures than do chemical methods,
when applied to nanoparticle arrays, forms new nanostructures with tunable properties.""There is a great potential market for this technology,
Propinquity creates conditions that produce nanorods, nanowires and nanosheets at chosen thicknesses and lengths rather than the one-size-fits-all output of a chemical process, with no environmentally harmful residues.
While experiments reported in the paper were performed with silverhe most desirable metal because it is the most conductive,
and mechanically stable nanostructures that no longer need restraining surfaces. These cannot be manufactured using current chemical methods.
composition and phase orientation of the initial nanoparticle arrays, a variety of nanostructures or nanocomposites and 3-D interconnected networks are achievable.
#Eco-friendly versatile nanocapsules developed The Institute for Basic Science (IBS) has announced that the Centre for Self-assembly
and Complexity have succeeded in developing a new technology that introduces metal nanoparticles on the surface of polymer nanocapsules made of cucurbit 6 uril.
The researchers have found that using polymer nanocapsules made of cucurbit 6 uril and metal salts can serve as a versatile platform where equal sized metal nanoparticles can be distributed evenly on the surface of the polymer nanocapsules.
Cucurbit 6 uril has properties which strongly and selectively recognize organic and inorganic chemical species. This makes it possible to use it as a protecting agent
The metal nanoparticle-decorated polymer nanocapsules exhibit the following properties in water: high stability for up to 6 months;
For example, the lotus can realize the self-cleaning effect using its micro/nanocomposite structure. The water striders can walk easily
and freely on the water surface via the special micro-and nanostructure on their legs.
Recently, Jiang's group focused on the confined water in one dimensional nanostructure materials. The study examined the confined water on the outer surfaces of one dimensional nano-structured materials including spider silk and cactus thorn,
and cactus thorn showed the confined water collection on these one dimensional nanostructures was helpful in solving the shortage of freshwater resources.
when you shoot multiwalled carbon nanotubes (MWCNTS) out of a gun onto an aluminum target at a velocity of more than 15000 mph?
If a nanotube reaches the target at a 90â°angle (head-on) it will break and deform quite drastically.
However if it is parallel to the target upon impact the nanotube will unzip resulting in a 2d graphene nanoribbon.
since previous simulations have shown that nanotubes break into pieces when subjected to large mechanical forces. Researchers Sehmus Ozden et al. at Rice university in Houston Texas US;
and the Indian Institute of Science in Bangalore India have published a paper on the results of their high-impact nanotube collision experiments in a recent issue of Nano Letters.
Because it was not possible to directly observe the impact due to the nanotubes'small size
and high speed the researchers analyzed the differences in the nanotubes using a transmission electron microscope before and after the impact to extract useful information about
Although each bundle of nanotubes (the pellet) was shot perpendicular to the target the individual randomly aligned nanotubes impacted the target at different angles.
At a 90â°impact angle the nanotubes deformed along the radial direction essentially being smashed like the front of a car in a head-on collision.
At a 45â°impact angle the nanotubes became partly deformed and partly unzipped. At a 0â°angle the nanotubes were unzipped completely
when shot at the aluminum target. The researchers explain that the unzipping occurs on the scale of femtoseconds.
In that short time many atoms along the side of the nanotube become stressed due to the impact resulting in the breaking of the carbon bonds in a straight line along the side of the nanotube.
Many of these atoms ended up being ejected from the nanotube rather than having their bonds neatly broken as in the 0â°impact angle scenario.
By demonstrating for the first time that nanotubes can be unzipped quickly through mechanical means the new study offers a clean-cut a clean chemical-free way to produce high-quality graphene nanoribbons.
As the researchers explained graphene nanoribbons have certain advantages over both nanotubes and graphene that make them attractive for applications.
Hybrid nanotube-graphene material promises to simplify manufacturing More information: Sehmus Ozden et al. Unzipping Carbon nanotubes at High Impact.
Adding silver nanorods to the graphene film would increase the conductivity to the same as copper,
Quantum dots are novel nanostructures that can become the basis of the next generation of solar cells capable of squeezing additional electricity out of the extra energy of blue and ultraviolet photons.
A new study conducted within the Center for Advanced Solar Photophysics demonstrates that appropriately engineered core/shell nanostructures made of lead selenide
and should be realizable with other combinations of materials and/or nanostructure geometries. Jeff Pietryga lead CASP chemist says Further enhancement in carrier multiplication should be possible by combining this new approach with other demonstrated means for increasing multicarrier yields such as by using shape-control
(as in nanorods) and/or materials in which cooling is already naturally slower like Pbte.
Applied together these strategies might provide a practical route to nanostructures exhibiting carrier multiplication performance approaching the limits imposed by energy conservation n
researchers from the USC Viterbi School of engineering describe how they have overcome a major issue in carbon nanotube technology by developing a flexible,
energy-efficient hybrid circuit combining carbon nanotube thin film transistors with other thin film transistors. This hybrid could take the place of silicon as the traditional transistor material used in electronic chips,
and Jialu Zhang developed this energy-efficient circuit by integrating carbon nanotube (CNT) thin film transistors (TFT) with thin film transistors comprised of indium, gallium and zinc oxide (IGZO)."
Instead of working so hard to force nanotubes to do something that they are not good for,
This hybridization of carbon nanotube thin films and IGZO thin films was achieved by combining their types, p-type and n-type, respectively,
Zhou likened the coupling of carbon nanotube TFTS and IGZO TFTS to the Chinese philosophy of yin and yang."
With this development, Zhou and his team have circumvented the difficulty of creating n-type carbon nanotube TFTS
and p-type IGZO TFTS by creating a hybrid integration of p-type carbon nanotube TFTS and n-type IGZO TFTS and demonstrating a large-scale integration of circuits.
Up to this point, all carbon nanotube-based transistors had a maximum number of 200 transistors.""We believe this is a technological breakthrough,
"The next step for Zhou and his team will be to build more complicated circuits using a CNT
"Zhou and Chen believe that carbon nanotube technology, including this new CNT-IGZO hybrid, will be commercialized in the next 5-10 years."
"I believe that this is just the beginning of creating hybrid integrated solutions, "said Zhou.""We will see a lot of interesting work coming up. g
#Charging portable electronics in 10 minutes Researchers at the University of California Riverside Bourns College of Engineering have developed a three-dimensional silicon-decorated cone-shaped carbon nanotube cluster architecture for lithium ion battery anodes that could enable charging of portable
In a paper Silicon Decorated Cone Shaped Carbon nanotube Clusters for Lithium ion battery Anode recently published in the journal Small UC Riverside researchers developed a novel structure of three-dimensional silicon decorated cone-shaped
carbon nanotube clusters architecture via chemical vapor deposition and inductively coupled plasma treatment. Lithium ion batteries based on this novel architecture demonstrate a high reversible capacity and excellent cycling stability.
special fibers could also be developed with nanostructures to conduct and store energy. More immediate applications could be seen in the design
#Atomic force microscope systems take a tip from nanowires (Phys. org) In response to requests from the semiconductor industry a team of PML researchers has demonstrated that atomic force microscope (AFM) probe
tips made from its near-perfect gallium nitride nanowires are superior in many respects to standard silicon
In addition the scientists have invented a means of simultaneously using the nanowire tips as LEDS to illuminate a tiny sample region with optical radiation
That technique called near-field scanning microwave microscopy (NSMM) had never before been attempted using a nanowire probe.
But as the team showed in a recent paper in Applied Physics Letters nanowire probe tips substantially outperformed commercial Pt tips in both resolution and durability.
and Synthesis of 3d Nanostructures in the Quantum Electronics and Photonics Division is that if you deform them even a little bit
By contrast our nanowire probe tips have a calibration lifetime about 10 times longer than any commercial tip.
The nanowire however retained its original dimensions. Moreover the Gan tips exhibited improved sensitivity and reduced uncertainty compared to a commercial Pt tip.
and negative charge carriers inside a nanostructure#information of great practical significance to microdevice fabricators#and scientists from PML's Electromagnetics Division have made notable progress in the technique.
They believe that the use of nanowire probes in conjunction with the recent arrival of a brand-new custom-built four-probe NSMM instrument will reveal new aspects of nanostructure composition and performance.
Deploying a nanowire as a probe tip sounds deceptively simple. The researchers obtain a conventional AFM cantilever
Then using a minuscule manipulator they break off a single nanowire from a forest of them grown by molecular beam epitaxy insert the wire into the hole and weld it in place.
The researchers tested their tip against a silicon tip a platinum tip and an uncoated Gan nanowire each
The coated nanowire proved about twice as sensitive as the Pt probe and four times as sensitive as the others with superior mechanical performance.
Using the nanowire tip as a light source by doping it so that it functions as an LED.
Reaching that goal will require more research into how to dope the Gan nanowires so as to increase efficiency of light output
But we really weren't able to test nanowires as probe tips until a few months ago
High-resolution microscopy technique resolves individual carbon nanotubes under ambient condition c
#DNA NANOTECHNOLOGY places enzyme catalysis within an arm's length Using molecules of DNA like an architectural scaffold, Arizona State university scientists,
"An even loftier and more valuable goal is to engineer highly programmed cascading enzyme pathways on DNA NANOSTRUCTURE platforms with control of input and output sequences.
The researchers also used tiny gold structures, known as plasmonic nanostructures, to focus the beams of light.
Just as a glass lens can be used to focus sunlight to a certain spot, these plasmonic nanostructures concentrate incoming light into hotspots on their surface,
"By using nanostructures, lasers and this unique twisting property of light, we could selectively destroy the unwanted form of the molecule,
The team created silicon dioxide (Sio2) nanotube anodes for lithium-ion batteries and found they had over three times as much energy storage capacity as the carbon-based anodes currently being used.
The paper,"Stable Cycling of Sio2 Nanotubes as High-performance Anodes for Lithium-Ion Batteries,"was published online in the journal Nature Scientific Reports.
but the ability to synthesize the material into highly uniform exotic nanostructures with high energy density
There key finding was that the silicon dioxide nanotubes are extremely stable in batteries, which is important
Specifically, Sio2 nanotube anodes were cycled 100 times without any loss in energy storage capability and the authors are highly confident that they could be cycled hundreds more times.
The researchers are focused now on developed methods to scale up production of the Sio2 nanotubes in hopes they could become a commercially viable product t
Nanosponge decoy fights superbug infections More information: Paper: Bio-inspired detoxification using 3d printed hydrogel nanocomposites www. nature. com/ncomms/2014/140full/ncomms4774. htm h
#Flexible supercapacitor raises bar for volumetric energy density Scientists have taken a large step toward making a fiber-like energy storage device that can be woven into clothing
A solution containing acid-oxidized single-wall nanotubes graphene oxide and ethylenediamine which promotes synthesis and dopes graphene with nitrogen is pumped through a flexible narrow reinforced tube called a capillary column and heated in an oven for six hours.
Sheets of graphene one to a few atoms thick and aligned single-walled carbon nanotubes self-assemble into an interconnected prorous network that run the length of the fiber.
and hyper-stretchable elastic-composite generator (SEG) using very long silver nanowire-based stretchable electrodes. Their stretchable piezoelectric generator can harvest mechanical energy to produce high power output (4 V) with large elasticity (250%)and excellent durability (over 104 cycles.
Instead, silicon nanopillars are arranged precisely into a honeycomb pattern to create a etasurfacethat can control the paths and properties of passing light waves.
#Pillared Graphene structures Gain Strength, Toughness and Ductility In a newly published study, scientists from Rice university reveal that putting nanotube pillars between sheets of graphene could create hybrid structures with a unique balance of strength, toughness
Carbon nanomaterials are common now as flat sheets, nanotubes and spheres, and theye being eyed for use as building blocks in hybrid structures with unique properties for electronics,
the way the atoms are arranged can influence all those properties. ome labs are actively trying to make these materials or measure properties like the strength of single nanotubes and graphene sheets,
and quantitatively predict the properties of hybrid versions of graphene and nanotubes. These hybrid structures impart new properties
and functionality that are absent in their parent structures graphene and nanotubes. To that end the lab assembled three-dimensional computer models of illared graphene nanostructures, akin to the boron nitride structures modeled in a previous study to analyze heat transfer between layers. his time we were interested in a comprehensive understanding of the elastic and inelastic properties
of 3-D carbon materials to test their mechanical strength and deformation mechanisms, Shahsavari said. e compared our 3-D hybrid structures with the properties of 2-D stacked graphene sheets and 1-D carbon nanotubes.
Turning the nanotubes in a way that forced wrinkles in the graphene sheets added further flexibility and shear compliance,
director of Berkeley Lab Materials sciences Division and a world authority on metamaterials artificial nanostructures engineered with electromagnetic properties not found in nature. ur ultra-thin cloak now looks like a coat.
director of Berkeley Lab Materials sciences Division and a world authority on metamaterials artificial nanostructures engineered with electromagnetic properties not found in nature. ur ultra-thin cloak now looks like a coat.
The idea is to mix nanotubes into a fluid to create a slurry, lay down a film just a few micrometers thick on a suitable substrate,
The heat-generating resistance comes mainly from the passage of current through gaps between the nanotubes.
when you combine some biomimicry, metamaterials and nanowires? It turns out to be integrated the first circularly polarized light detector on a silicon chip.
Researchers at Vanderbilt University have used silver nanowires to fabricate a metamaterial that is capable of detecting polarized light in a way not unlike the way cuttlefish, bees,
the researchers fabricated the portable CPL sensors by laying down nanowires in a zigzag pattern over a thin sheet of acrylic affixed to a thick silver plate.
This material is affixed to the bottom of a silicon wafer with the nanowire side up.
The nanowires create a sea of electrons that produces lasmondensity waves, the oscillations in the density of electrons that are generated
The researchers found that they could make the zigzag pattern of nanowires with a right-or left-handed orientation.
When they arranged the nanowires in right-handed pattern, the surface absorbed right circularly polarized light
And when they arranged the nanowires to have both left-and right-handed patterns, the sensor could discern between left
Until now, the only experimental TFET to meet the International Technology Roadmap for Semiconductors (ITRS) goal of average subthreshold swing below 60 millivolts per decade over four decades of current was a transistor that used nanowires.
Screen Shot 2015-05-04 at 7. 29.15 AM To create the nanofiber thin membrane that could be produced at scale,
the primary component of natural gas, using a combination of semiconducting nanowires and bacteria. The research builds on a similar hybrid system that yielded butanol, a component in gasoline,
"The Calverton, New york-based Graphene 3d Lab is already well-known for the development of proprietary graphene-based nanocomposite materials for 3d printing,
and scaffolds with the required shapes and sizes. he carbon nanotubes (or CNT) were added to the bioprintable material mixture to create a hree-dimensional electrical conducting network all through the volume of the scaffold,
CNTS are basically one-atom-thick graphene sheets rolled up onto themselves in order to form very long filaments with diameters of only a few nanometers. n this sense,
by adding conducting CNTS into the bioprinted polymer and mineral prosthetic bone implant, you can stimulate the regrowth of the actual bone cells.
Perhaps one of the most curious aspects is that bioprinting CNTS created no additional difficulties,
the addition of the CNTS was performed and reaching a proper dispersion took a bit of stirring time. ercedes
#Tiny'Nanoneedles'Prompt Parts of the Body to Generate New Blood vessels The researchers, from Imperial College London and Houston Methodist Research Institute in the USA, hope their nanoneedle technique could ultimately help damaged organs
and nerves to repair themselves and help transplanted organs to thrive. The nanoneedles work by delivering nucleic acids to a specific area.
Nucleic acids are the building blocks of all living organisms and they encode, transmit and express genetic information.
The nanoneedles are tiny porous structures that act as a sponge to load significantly more nucleic acids than solid structures.
The nanoneedles are made from biodegradable silicon, meaning that they can be left in the body without leaving a toxic residue behind.
and sirna into human cells in the lab, using the nanoneedles. They also showed they could deliver nucleic acids into the back muscles in mice.
using nanoneedles, to provide transplanted organs or future artificial organ implants with the necessary connections to the rest of the body,
but we are pleased that the nanoneedles have been successful in this trial in mice. There are a number of hurdles to overcome
and we haven't yet trialled the nanoneedles in humans, but we think they have enormous potential for helping the body to repair itself."
"The researchers are now aiming to develop a material like a flexible bandage that can incorporate the nanoneedles.
Alternatively, we may see surgeons first applying the nanoneedle bandages inside the affected region to promote the healthy integration of these new organs and implants in the body.
#Breakthrough, Low-cost Method to Build DNA NANOTUBES Block By Block Researchers at Mcgill University have developed a new,
low-cost method to build DNA NANOTUBES block by block a breakthrough that could help pave the way for scaffolds made from DNA strands to be used in applications such as optical and electronic devices or smart drug-delivery systems.
have constructed previously nanotubes using a method that relies on spontaneous assembly of DNA in solution.
we can now build long nanotubes block by block, said Amani Hariri, a Phd student in Mcgill Department of chemistry and lead author of the study. y using a fluorescence microscope we can further visualize the formation of the tubes at each stage of assembly,
The custom-built assembly technique developed through this collaboration ives us the ability to monitor the nanotubes as wee building them,
The resulting esigner nanotubes she adds, promise to be far cheaper to produce on a large scale than those created with so-called DNA origami,
Nanocomposite Technology, Interface Materials, and Bio Interfaces. Source: http://www. inm-gmbh. de e
#Cerium-Based Material Made into Nanometer-Sized Particles to Produce Key Ingredient for Nylon Production The Critical Materials Institute,
The University of Manchester in Manchester, UK has performed 3d in situ imaging of crack growth using Xradia Ultra Load Stage in nanoindentation mode to understand how cracks grow in dentin, the nanocomposite that forms the bulk of teeth.
and quantifying 3d nanostructures under load. This is a completely unique capability that offers new opportunities to connect small scale evolution processes with those observed in micron scale XRM and bulk material testing."
#Innovative Fabrication Technique for Hybrid Nanostructure Supercapacitor Electrode Offsetting this promise is the fact that,
Now two researchers from the S n. Bose National Centre for Basic Sciences, India, have developed a novel supercapacitor electrode based on a hybrid nanostructure made from a hybrid nickel oxide-iron oxide
from AIP Publishing, the researchers report the fabrication technique of the hybrid nanostructure electrode. They also demonstrate its superior performance compared to existing, non-hybrid supercapacitor electrodes.
National Centre for Basic Sciences, mixed nickel oxide and iron oxide as a hybrid material and fabricated the novel core/shell nanostructure electrode."
In Singh's experiment, the core/shell hybrid nanostructure was fabricated through a two-step method. Using a standard electro-deposition technique,
the researchers grew arrays of iron-nickel nanowires inside the pores of anodized alumina oxide templates,
then dissolved the templates to obtain the bare hybrid nanowires. After that, the researchers exposed the nanowires in an oxygen environment at high temperature (450 degreescelsius) for a short time,
eventually developing a highly porous iron oxide-nickel oxide hybrid shell around the iron-nickel core."
"The advantage of this core/shell hybrid nanostructure is that the highly porous shell nanolayer provides a very large surface area for redox reactions
and iron/iron oxide core/shell nanostructure electrodes, the hybrid material electrode demonstrated higher capacitance,
"The remarkable electrochemical performances and material properties suggest that the iron oxide-nickel oxide hybrid core/shell nanostructure could be a reliable and promising candidate for fabricating the next generation lightweight, low-cost
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