Tropes

phys_org 00167.txt

#A simple and versatile way to build 3-dimensional materials of the future Researchers in Japan have developed a novel yet simple technique called diffusion driven layer-by-layer assembly to construct graphene into porous three-dimensional (3d) structures for applications in devices such as batteries and supercapacitors. Their study was published recently in the journal Nature Communications. Graphene is essentially an ultra-thin sheet of carbon and possesses exciting properties such as high mechanical stability and remarkable electrical conductivity. It has been touted as the next generation material that can conceivably revolutionize existing technology and energy sectors as we know them. However the thin structure of graphene also acts as a major obstacle for practical uses. When piecing together these tiny sheets into larger structures the sheets easily stack with one another resulting in a significant loss of unique material properties. While several strategies have been proposed to deal with this sticky issue they are often costly time consuming and difficult to scale up. To overcome this challenge the researchers from the Institute for Integrated Cell-Material Sciences (icems) at Kyoto University borrowed a principle from polymer chemistry and developed it into a technique to assemble graphene into porous 3d architectures while preventing stacking between the sheets. By putting graphene oxide (an oxidized form of graphene) into contact with an oppositely charged polymer the two components could form a stable composite layer a process also known as interfacial complexation. Interestingly the polymer could continuously diffuse through the interface and induce additional reactions which allowed the graphene-based composite to develop into thick multilayered structures. Hence we named this process'diffusion driven layer-by-layer assembly'explained Jianli Zou a co-investigator in the project. The resulting products display a foam-like porous structure ideal for maximizing the benefits of graphene with the porosity tunable from ultra-light to highly dense through simple changes in experimental conditions. Furthermore the process is easily scalable for creating large-area films which will be highly useful as electrodes and membranes for energy generation or storage. While we have demonstrated only the construction of graphene-based structures in this study we strongly believe that the new technique will be able to serve as a general method for the assembly of a much wider range of nanomaterials concluded Franklin Kim the principal investigator of the study y

< Back - Next >