Tropes

R_www.technology.org 2015 13963.txt.txt

#Scientists grow organic semiconductor crystals vertically for first time Our smartphones, tablets, computers and biosensors all have improved because of the rapidly increasing efficiency of semiconductors. Since the turn of the 21st century, organic, or carbon-based, semiconductors have emerged as a major area of interest for scientists because they are inexpensive, plentiful and lightweight, and they can conduct current in ways comparable to inorganic semiconductors, which are made from metal-oxides or silicon. Now, materials scientists from the California Nanosystems Institute at UCLA have discovered a way to make organic semiconductors more powerful and more efficient. Their breakthrough was in creating an improved structure for one type of organic semiconductor a building block of a conductive polymer called tetraaniline. The scientists showed for the first time that tetraaniline crystals could be grown vertically. The advance could eventually lead to vastly improved technology for capturing solar energy. In fact, it could literally reshape solar cells. Scientists could potentially create ight antennasthin, pole-like devices that could absorb light from all directions, which would be an improvement over today wide, flat panels that can only absorb light from one surface. The study, led by Richard Kaner, distinguished professor of chemistry and biochemistry and materials science and engineering, was published recently by the journal ACS Nano. The UCLA team grew the tetraaniline crystals vertically from a substrate so the crystals stood up like spikes instead of lying flat as they do produced when using current techniques. They produced the crystals in a solution using a substrate made of graphene, a nanomaterial consisting of graphite that is extremely thin measuring the thickness of a single atom. Scientists had grown previously crystals vertically in inorganic semiconducting materials, including silicon, but doing it in organic materials has been more difficult. Tetraaniline is a desirable material for semiconductors because of its particular electrical and chemical properties, which are determined by the orientation of very small crystals it contains. Devices such as solar cells and photosensors work better if the crystals grow vertically because vertical crystals can be packed more densely in the semiconductor, making it more powerful and more efficient at controlling electrical current. hese crystals are analogous to organizing a table covered with scattered pencils into a pencil cup, said Yue essicawang, a former UCLA doctoral student who now is a postdoctoral scholar at Stanford university and was the study first author. he vertical orientation can save a great deal of space, and that can mean smaller, more efficient personal electronics in the near future. Once Kaner and his colleagues found they could guide the tetraaniline solution to grow vertical crystals, they developed a one-step method for growing highly ordered, vertically aligned crystals for a variety of organic semiconductors using the same graphene substrate. he key was deciphering the interactions between organic semiconductors and graphene in various solvent environments, Wang said. nce we understood this complex mechanism, growing vertical organic crystals became simple. Kaner said the researchers also discovered another advantage of the graphene substrate. his technique enables us to pattern crystals wherever we want, he said. ou could make electronic devices from these semiconductor crystals and grow them precisely in intricate patterns required for the device you want, such as thin-film transistors or light-emitting diodes. a

< Back - Next >