Synopsis: Chemistry & chemical compounds: Chemistry & chemicals:


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and determined the mechanism of crystallization the polymer chemist adds. Vertical nanopillars are ideal geometries for getting around these challenges Briseno says


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The study thought to be the first to assess these compounds in apple cultivars grown in the Pacific Northwest appears in October's print edition of the journal Food Chemistry.


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while nitrogen pollution has changed soil chemistry in Canada and Panama. Continents apart these changes have all been documented by the Smithsonian-led Center for Tropical forest Science-Forest Global Earth Observatory CTFS-Forestgeo

Many of the changes occurring in forests worldwide are attributable to human impacts on climate atmospheric chemistry land use


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#Goats better than chemicals for curbing invasive marsh grassherbivores not herbicides may be the most effective way to combat the spread of one of the most invasive plants now threatening East Coast salt marshes a new Duke university-led

Land managers traditionally have used chemical herbicides to slow phragmites'spread but with only limited and temporary success. Now field experiments by researchers at Duke

For more than two decades we've declared major chemical and physical warfare on this grass using all the latest humanmade weapons Silliman said.


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But sugars may also be part of a deadly game of tag between plant and insect according to scientists at the Max Planck Institute for Chemical Ecology.

Like all cereals and other members of the grass family maize plants defend themselves with chemistry.

and Jonathan Gershenzon from the Department of Biochemistry at the Max Planck Institute for Chemical Ecology in Jena Germany have discovered recently a previously unknown detoxification strategy in these pest insects.

Modern and highly sensitive mass spectrometry and nuclear magnetic resonance spectroscopy methods showed that the benzoxazinoid identified in the larval frass was no longer identical to the substance in the plant leaves.

The importance of the three-dimensional structure of molecules and the stereospecificity of chemical reactions is overlooked often.

The chemical chirality of the compounds is the key here explains Jonathan Gershenzon director of the Department of Biochemistry.

These insects can teach us humans a lot about an important chemical concept the idea that a compound

The above story is provided based on materials by Max Planck Institute for Chemical Ecology. Note: Materials may be edited for content and length.


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Moreover the surface chemistry of biochar--both on external surfaces and inside pores--is likely to promote absorption and further slow the movement of water.


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and atmospheric moisture future satellites will also use'chemical cameras'to map the distributions of greenhouse gases

CLARS provides a way to test this by mapping chemicals in the air over Los angeles. The methods we're testing today can ultimately fill a critical need for decision makers to determine


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Patients with kidney disease can use dialysis and those with cardiac problems have ventricular assist devices

Liver failure patients and their doctors have long been frustrated by the critical need to provide the kind of lifesaving care kidney patients are afforded by dialysis.


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#Graphene imperfections key to creating hypersensitive electronic noseresearchers have discovered a way to create a highly sensitive chemical sensor based on the crystalline flaws in graphene sheets.

A theoretical chemistry group at UIC led by Petr Kral was able to explain this attraction and additional electronic properties of the grain boundary.


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and that somehow the leaves transmit the information to the roots using an unknown chemical mechanism to signal that the plant should develop


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Together with her colleague from GÃ rlitz Dr. John M. C. Hutchinson and a colleague from the United states Department of agriculture (USDA-APHIS) the scientist has studied the distribution of these mollusks

and whether its expansion is correlated to specific climate factors explains Hutchinson the paper's lead author.

and Eastern europe a wide berth says Hutchinson and he adds We assume that the cold winters in the eastern countries

In principle all areas with a temperate climate can serve as potential habitat for these animals says Hutchinson and offers the following recommendation:


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The technology was introduced this month in the American Chemical Society journal Applied materials and Interfaces. The material is made of graphene nanoribbons atom-thick strips of carbon created by splitting nanotubes a process also invented by the Tour lab

and Vladimir Volman an engineer at Lockheed martin. Tour is the T. T. and W. F. Chao Chair in Chemistry as well as a professor of materials science and nanoengineering and of computer science.


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And their studies suggest that these methods could be as efficient in protecting crops as using chemical based pesticides.

and reduce the usage of chemicals at the same time. Watch video: http://www. youris. com/Bioeconomy/BIOECONOMY-TV/Reducing-Pesticides-And-Boosting-Harvests. kl#ixzz3dugjrct2story Source:


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and chemical engineer Matteo Pasquali a co-author on the new paper used an acid dissolution process to keep the nanotubes separated until they could be spun into fibers.

Professor in Mechanical engineering and Materials Science and of chemistry and chair of the Department of Materials Science and Nanoengineering.

Pasquali is chair of the Department of chemistry and a professor of chemical and biomolecular engineering of materials science and nanoengineering and of chemistry.

Martã is an assistant professor of chemistry and bioengineering and of materials science and nanoengineering. The Welch Foundation supported the research.


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and chemicals deep into underground rock formations are the subject of new research that synthesizes 165 academic studies and government databases.

Gas and chemicals from humanmade fractures thousands of meters underground very rarely seep upward to drinking-water aquifers the study says.

Wastewater disposal is one of the biggest issues associated with fracking said co-author Avner Vengosh a professor of geochemistry at Duke university.

or sent to municipal water-treatment plants not equipped to handle the chemicals involved. All bad ideas according to the authors of the new survey who work at Duke university MIT Ohio State university Newcastle University Los alamos National Laboratory the National Oceanic and Atmospheric administration and Stanford.


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the only options for control of the pest farmers have had are highly toxic chemicals many of them severely restricted.

therefore a biological pest control was achieved the use of chemicals ceased and agriculture on the region improved.

and to perform research focused on the generation of biological pesticides which is a very important issue for agriculture due to the increasing restriction on the use of chemical pesticides emphasizes the scientist at INECOL.


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or skeletal material (via calcification) depends on the abundance of carbonate ion. For many organisms calcification declines with increased acidification.

Other impacts of acidification include reduced survival development and growth rates as well as changes in physiological functions and reduced biodiversity.


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The research team of Annette Rompel from the Institute for Biophysical Chemistry University of Vienna explore the mechanisms behind the browning reaction during the spoilage of mushrooms.

This precursor is activated then via specific chemical cleavage. At this cleavage site the protein segment covering part of the enzyme active site is removed

and take part in key chemical reactions. New Method of Isolation and unique reagent leads to successnone of the previously established methods of isolation present in the literature could be applied successfully for PPO4.

For the first time at the Institute for Biophysical Chemistry of the University of Vienna a method was developed that allows for the one stage isolation of latent tyrosinase from their natural source.

The enzyme characterization was undertaken at the Department of chemistry with close cooperation with the Institute of Mass Spectrometry lead by Andreas Rizzi both within the University of Vienna.

and optimize appropriate crystallization conditions which produced well formed protein crystals. This was only possible with the use of a relatively unusual co-crystallization reagent a polyoxometalate of the Anderson type.

Integral for medicine and biotechnologythe Phd student Stephan Mauracher worked at the University of Vienna taking an essential part in this project as part of the University Initiative termed Functional Molecules.

and was a key proponent of its usage as an additive for protein crystallization. The research project was continued then as FWF Initiative.

This research has allowed for the crystallization and three-dimensional structure of PPO4 to be resolved says Anette Rompel.


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In a paper in the American Chemical Society journal Nano Letters the Rice team analyzed the properties of elemental bonds between semiconducting phosphorus atoms in 2-D sheets.

Yakobson is Rice's Karl F. Hasselmann Professor of Materials Science and Nanoengineering a professor of chemistry and a member of Rice's Richard E. Smalley Institute for Nanoscale Science and Technology.


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and grasslands and replaced them with croplands said Unger an assistant professor of atmospheric chemistry at F&es.

Not all of these compounds affect atmospheric chemistry in the same way. Aerosols for instance contribute to global cooling


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#Coffee genome sheds light on the evolution of caffeinethe newly sequenced genome of the coffee plant reveals secrets about the evolution of man's best chemical friend:

Scientists theorize that the chemical may help plants repel insects or stunt competitors'growth. One recent paper showed that pollinators--like humans--may develop caffeine habits.


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when nitrogen oxides carbon monoxide and volatile organic compounds react with sunlight after the chemicals'release from vehicles industry or burning of wood or other plant or animal matter.


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To overcome PIM-1's weaknesses Sivaniah's team heated PIM-1 at temperatures ranging from 120 to 450 °C in the presence of oxygen a process referred to as thermal oxidation.


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and biology its chemical ecology and the types of damage it does to various host plants.

They also discuss different chemical control options that can be used successfully in integrated pest management programs.

To return to an integrated approach to managing all pests in the crops affected by H. halys growers require a more sustainable strategy for chemical control that combines efficient use of insecticides with a better understanding of its biology and behavior according to the authors.


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Results indicated that it pays off to maintain chemical free greenhouse crop production. If biological pest control was used whitefly populations were more susceptible to insecticides


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He collaborates with carbon emissions expert Robert Yokelson a chemistry professor from the University of Montana.


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The work reported this month in the Journal of the American Chemical Society (JACS) focused on a tetracycline discovered in 2008 by scientists who isolated small amounts from penicillium fungi.

One was to develop new synthetic chemistry which is always the case in these kinds of endeavors.

The interface between chemistry and biology is the key to success in discovering drugs. Co-authors of the JACS paper are graduate students Christopher Hale Lizanne Nilewski and Kathryn Beabout and postdoctoral fellows Christian Nilewski Heraklidia Ioannidou and Abdelatif El Marrouni all of Rice

Nicolaou is the Harry C. and Olga K. Wiess Professor of Chemistry. Story Source: The above story is provided based on materials by Rice university.


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when the plant gets a chemical signal from the bacterium --but the growing tube inside the root hair that accepts the bacteria requires something else

This dual requirement for chemical and mechanical signals is present in both associations even though the association between rhizobia and legumes is only 60 million years old.


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An organic residue analysis using mass spectrometry revealed that all of the relatively uniform jars contained chemical compounds indicative of wine.


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and Food Chemistry could help prevent organic food fraud. Researchers from the Bavarian Health and Food safety Authority and the Wuerzburg University note that the demand for organic food is growing at a rapid clip.

They looked to a technique called nuclear magnetic resonance spectroscopy which has been used to authenticate foods including honey and olive oil.

The above story is provided based on materials by American Chemical Society. Note: Materials may be edited for content and length.


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and evaluations at the MU Research Reactor Analytical Chemistry facility and at MU Plant and Soil Analysis Facility the study team drew conclusions that will help corn producers make informed decisions about raising


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However the statement stresses that clinicians be educated so they can inform patients that e-cigarettes are unregulated may contain low levels of toxic chemicals

Nicotine is a dangerous and highly addictive chemical no matter what form it takes--conventional cigarettes


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It might have been the noise of the spray that stopped them and not the chemical. Mcglone asked Sergeant's to make several spray cans that had the androstenone in different concentrations


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That's a massive number of naturally occurring variants a lot in cell wall chemistry genes and other known productivity genes.


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The above story is provided based on materials by American Chemical Society. Note: Materials may be edited for content and length.


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Wildland fires involve complex interactions that include fuel distribution terrain topography chemical reactions energy transfer and the associated fluid dynamics that transport moisture gas-phase hydrocarbons air

burns to help develop models describing the chemistry and fluid dynamics of fires. His interest was sparked.

Continual warming of the leading edge of the fire is a necessary precondition to releasing the chemicals in the fuels that are needed to sustain it.


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Hormones chemical messengers that are activated in direct response to light and temperature stimuli help them achieve this.


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This is known as spectroscopy and it is one of the most important tools that an astronomer has for studying the universe.

if there is a chemical relationship with their rotation speeds. While constructing the catalog Hinkel noticed that the stars in the solar neighborhood reveal unexpected compositions


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says Blake Simmons a chemical engineer who is JBEI's Chief Science and Technology Officer and heads JBEI's Deconstruction Division.

and synthesizing them into fuels and other valuable chemical products. A major challenge has been that unlike the simple sugars in corn grain the complex polysaccharides in biomass are embedded deeply within a tough woody material called lignin.


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and a production process using various toxic chemicals. As well as providing significant environmental benefits by reducing reliance on fossil fuels a successful digestate-ash fertilizer would also reduce costs

http://www. lancaster. ac. uk/media/lancaster-university/content-assets/documents/lec/business/LEC-NERC-Catalyst-Project. pdfstory Source:


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and identify out of place-place molecules on its surface through terahertz spectroscopy. They expect the finding to be important to manufacturers considering the use of graphene in electronic devices.

The experiment involved growing pristine graphene via chemical vapor deposition and transferring it to an indium phosphide substrate.

and Robert Vajtai a senior faculty fellow and Pulickel Ajayan the Benjamin M. and Mary Greenwood Anderson Professor in Engineering professor of materials science and nanoengineering and of chemistry and chair


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Populations of healthy males and females can be produced in controlled environments by the addition of a chemical repressor.

If the chemical repressor is absent in the genetically engineered fliesâ##diet only males survive.


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Their report will be part of the 248th National Meeting & Exposition of the American Chemical Society (ACS.

In contrast the new test uses liquid chromatography and statistical tools. This gives her team a much closer look at the ingredients in an unbiased way according to Nixdorf.

Chromatography is a powerful analytical technique that is very sensitive and highly selective. Because much of the coffee is composed of carbohydrates researchers could develop a characteristic fingerprint

when using chromatography that separates out the real coffee compounds says Nixdorf. The added unwanted grain fillers generate different levels of sugars than the natural ingredients

The above story is provided based on materials by American Chemical Society (ACS. Note: Materials may be edited for content and length h


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and Chemistry addresses the effects of two broad-spectrum systemic insecticides fipornil and imidacloprid on honeybees.

Mitochondria are the power plants of a cell generating most of a cell's supply of adenosine triphosphate (ATP) used as a source of chemical energy.

Mitochondrial oxidative phosphorylation drives ATP synthesis which is required to contract the muscles during flight. If something goes wrong the energy production is impaired explains Nicodemo.

The above story is provided based on materials by Society of Environmental Toxicology and Chemistry. Note: Materials may be edited for content and length.


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and lead author of the study published recently in Environmental Toxicology & Chemistry. The lack of any significant biomagnification through the food chain indicates that there is very little risk of harm from exposure to these CUPS in this region.

and other toxic chemicals such as PCBS found in wildlife and in Inuit and other aboriginal and non-aboriginal Northerners dependent on hunting Morris said.


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These genes play a key role in the most efficient type of energy generation in cells a process called oxidative phosphorylation.

In the new study postdoctoral researcher Clare Rittschof used drugs to suppress key steps in oxidative phosphorylation in the bee brains.

In separate experiments postdoctoral researcher Hongmei Li-Byarlay and undergraduate student Jonathan Massey found that reduced oxidative phosphorylation in fruit flies also increased aggression.

Using advanced fly genetics the team found this effect only when oxidative phosphorylation was reduced in neurons but not in neighboring cells known as glia.


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For example if conditions do not induce diseases growers sprayed unnecessarily wasting chemicals and labor and increasing production costs.

Third too much fungicide helps build chemical resistance for the disease Vansickle said. The study written by Vorotnikova Borisova


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Like eyes the phytochrome is a light sensor that converts sunlight into chemical signals to get these jobs done.


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and military troops exposed to poisonous chemicals--particularly those in pesticides and chemical weapons. An article in the current issue of the journal Chembiochem outlines the advancement in detoxifying organophosphates

The patent-pending process was developed by NYU School of engineering Associate professor of Chemical and Biological Engineering Jin Kim Montclare along with Richard Bonneau an associate professor in NYU's Department of biology and a member of the computer science faculty

which have the unique capability of degrading chemicals in a class known as organophosphates which are found in everything from industrial pesticides to the sarin gas used in chemical warfare.

and caustic chemical reagents for neutralization followed by hazardous materials disposal she said. These proteins could accomplish that same task enzymatically without the need for reactors and formation of dangerous byproducts.


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Professor Richard Evershed from the School of Chemistry said: It never ceases to amaze me that these sensitive chemical signatures of changing human life survive in the archaeological record for thousands of years.

And it leaves one pondering what was motivating the people to move into these challenging regions?


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and 16 flavones were identified tentatively from dried leaves of mas cotek using high performance liquid chromatography (HPLC) coupled to a photodiode array and electrospray ionization mass spectrometry.


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The use of clothianidin one of the chemicals studied on corn in Iowa alone has doubled almost between 2011 and 2013.

and the chemicals were found in all nine rivers and streams. Of the three most often found chemicals clothianidin was the most commonly detected showing up in 75 percent of the sites and at the highest concentration.

Thiamethoxam was found at 47 percent of the sites and imidacloprid was found at 23 percent.

One of the chemicals imidacloprid is known to be toxic to aquatic organisms at 10-100 nanograms per liter


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the nicotine levels carcinogens and chemical additive levels are unknown. The FDA recently proposed a new rule to extend their regulatory authority to cover alternative tobacco products including e-cigarettes cigars pipe tobacco and hookah tobacco.


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Hence one of the challenges in this field is the ability to create microdevices out of the Mos2 film comprising components with different thickness or chemical nature.

Further researchthe fast growing field of electronics and optoelectronics demands precise material deposition with application-specific optical electrical chemical and mechanical properties.


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and now widely banned pesticides and other toxic chemicals--called legacy contaminants--can become magnified in an animal that eats contaminated food.

'The study appears in the journal Environmental Toxicology & Chemistry. Researchers who studied the vegetation-caribou-wolf food chain in the Bathurst region of Canada say that currently use pesticides enter the food chain


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The substrates differed in infiltration and drainage rates as well as chemical composition. Diverse plant species that included trees shrubs herbaceous perennials a grass and a rush were selected to allow the researchers to evaluate the performance of a wide range of evergreen deciduous woody and herbaceous plants.


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Evolving a Taste for Toxinsmany plants produce toxic chemicals which they use as a defense against herbivores or plant-eating animals.

their bodies must handle up to hundreds of toxic chemicals from the plants they consume each day.


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Demand for natural food additivesrising health concerns about chemical additives have strengthened demand for natural food additives said co-author Meijun Zhu an assistant professor in the School of Food Science.


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or chemicals that tell others of their species to come closer. Scientists could potentially use the substances to lure brown marmorated stink bugs to a specific spot

and reported the chemical architectures of two pheromone components. They did this by studying closely related compounds.

The above story is provided based on materials by American Chemical Society. Note: Materials may be edited for content and length.


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The research was carried out by York's Wolfson Atmospheric Chemistry laboratories the National Centre for Atmospheric Science

and the Chromatography and Environmental Applications research group at the Universitat Rovira i Virgili Spain.

Lead investigator Dr Jacqueline Hamilton from York's Wolfson Atmospheric Chemistry laboratories said: The risks of tobacco exposure do not end

Professor Alastair Lewis from York's Wolfson Atmospheric Chemistry laboratories and the National Centre for Atmospheric Science said:

Measurements were made using a comprehensive two-dimensional gas chromatography system which was funded originally by NERC to study particulate matter in the atmosphere.

Dr Noelia Ramirez a Postdoctoral Research Fellow from York's Wolfson Atmospheric Chemistry laboratories who started this research line said:


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As a result the harvested portion of the plant will often contain lower concentrations of other nutrients including health-promoting antioxidants Without the synthetic chemical pesticides applied on conventional crops organic plants also tend to produce more phenols


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In a new paper available online in the American Chemical Society journal Nano Letters a Rice team led by chemist James Tour compared its RRAM technology to more than a dozen competing versions.

Tour is Rice's T. T. and W. F. Chao Chair in Chemistry and professor of mechanical engineering and nanoengineering and of computer science.

and Edwin Thomas the William and Stephanie Sick Dean of Rice's George R. Brown School of engineering professor in mechanical engineering and materials science and in chemical and biomolecular engineering.


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Chemical control poses a considerable risk to non-target species such as endemic ants. The study therefore advises promoting


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and tannins increasing its antioxidant potential explains Amparo Quiles researcher at the Group of Microstructure and Food Chemistry of the Universitat Politã cnica de Valã ncia.


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Although pesticide exposure has been implicated as a possible cause for bee decline until now we had limited understanding of the risk these chemicals pose especially how it affects natural foraging behaviour Raine said.


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Gradual degeneration of these cells causes a reduction in a vital chemical neurotransmitter dopamine. The decrease in dopamine results in one or more of the classic signs of Parkinson's disease that includes:


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and 35 percent said they thought that fruit used to flavor the tobacco detoxify tobacco's harmful chemicals.


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In chemistry ph is a measure of the acidity of a solution. As each SPOT monitors


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Two teams are interested in rust in space St peter's School students in Kansas city Missouri want to determine how microgravity affects oxidation


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but have lost their ability to produce certain defense chemicals making them vulnerable to attack by insects and pathogens.

Swiss scientists are exploring ways to help protect 21st century maize by rearming it with its ancestral chemical weapons.

The researchers led by Dr Ted Turlings (University of Neuchã¢tel Switzerland) found that many varieties of modern maize have lost their ability to produce a chemical called E-Î-caryophyllene.

This chemical is produced normally by traditional ancestors of modern maize roots when the plant is under attack from invading corn rootworms.

The chemical attracts'friendly'nematode worms from the surrounding soil which in turn kill the corn rootworm larvae within a few days.

One of the types of toxins that maize plants produce against their enemies is a class of chemicals called benzoxazinoids.


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and assistant professor Adam Hoppe of SDSU Chemistry and Biochemistry Department are examining how BVDV suppresses the cow's immune response.


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The researchers used stable isotope analysis a chemical assay of a tissue biopsy that provides an integrative view of what the animal ate in previous months.

They matched the chemical signature of the mantas to that of zooplankton collected in the lagoons verifying that this habitat serves as an important feeding ground.


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Publishing in Analytical Chemistry EPFL scientists have developed a highly sensitive method that can quickly and accurately identify the culprit proteins even at very low concentrations.

The beads are washed then with a strong chemical that causes the allergy-inducing protein to dissociate from the patient's Ige antibodies.

The isolated culprit protein is identified then using mass spectrometry which is a technique that analyzes compounds according to their mass and electrical charge.


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while the carbon amassed in soils invaded by knotweed is more prone to oxidation and is lost subsequently to the atmosphere.

The key seems to be how plant litter chemistry regulates the soil biological activity that facilitates the buildup composition and stability of carbon-trapping organic matter in soil.

and suggest that it is the chemistry of plant biomass added to soil rather than the total amount of biomass that has the greatest influence on the ability of soil to harbor stable carbon.

and research team at Clemson that studies how the chemical and biological interactions that take place in the plant-soil interface shape plant communities.


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